Solid State Ionics, Vol.141-142, 541-548, 2001
Synthesis of highly tailored ceramic matrix composites by pressure-pulsed CVI
Pressure-pulsed chemical vapor infiltration (P-CVI) is a new processing technique to produce ceramic matrix composites (CMCs) (C/C, C/SiC and SiC/SiC) from gaseous precursors with highly tailored interphases and matrices. P-CVI can be used to control the microtexture of pyrocarbon deposited from hydrocarbon in a porous body. It is also used to form (PyC-SiC)(n) or (BN-SiC)(n) interphases with elementary layer thickness of a few nanometers. Finally, P-CVI is an efficient way to produce self-healing matrices comprising mechanical fuse layers (PyC or BN) and glass-former layers (B13C2 or/and SiC). The resulting model or real composites display an oxidation resistance, in air at 600-700 degreesC and under load, which is improved by two orders of magnitude.
Keywords:chemical vapor infiltration;CVI;ceramic matrix composite;multilayered ceramics;carbon;silicon carbide;boron nitride