HWAHAK KONGHAK, Vol.39, No.6, 734-738, December, 2001
Ziegler-Natta 촉매 및 Metallocene 촉매로 제조된 PE 입자의 유동층에서의 공극률 특성
Characteristics of Bed Voidage in a Fluidized Bed of Polyethylene Particles Polymerized by Ziegler-Natta and Metallocene Catalysts
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초록
Ziegler-Natta 및 Metallocene 촉매로 기상유동층에서 중합된 polyethylene 입자의 공극률 특성을 높이 50 cm, 직경 7 cm의 유동층 실험장치에서 관찰하였다. 기체유속이 최소유동화 속도에서 난류유동화 속도까지 변화할 때 유동층 내에의 평균 공극률은 Metallocene 촉매로 중합된 PE의 경우 0.4-0.65이었고, Ziegler-Natta 촉매로 중합된 PE의 경우 0.4-0.85이었다. 입도분포가 비교적 넓은 Ziegler-Natta 촉매로 중합된 PE가 Metallocene 촉매로 중합된 PE 보다 압력변동의 폭이 작았으며, Metallocene 촉매로 중합된 PE에 Ziegler-Natta 촉매로 중합된 PE를 첨가함에 따라 압력변동의 폭이 감소하면서 공극률은 증가하였다.
The characteristics of bed voidage in a fluidized bed of polyethylene particles polymerized by metallocene and Ziegler-Natta catalysts were investigated in a fluidized bed of 7 cm I.D. and 50 cm in height. The average bed voidage for the ranges of gas velocity from minimum fluidization velocity to turbulent fluidization velocity were 0.4-0.65 for PE with Metallocene catalyst and 0.4-0.85 for PE with Ziegler-Natta catalyst. The pressure fluctuations were smaller for PE with Ziegler-Natta catalyst than that with Metallocene catalyst. The addition of PE with Ziegler-Natta catalyst to the PE with Metallocene catalyst reduced the pressure fluctuations and increased the bed voidage.
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