화학공학소재연구정보센터
Journal of Rheology, Vol.45, No.5, 1105-1122, 2001
A slotted plate device for measuring static yield stress
A slotted-plate device was constructed with a balance and a linear-motion platform to directly measure static yield stresses of suspensions by moving the plate in the suspension in a similar mode as is done in the well-known Withelmy-plate technique for measuring surface tension. Wall effects associated with the original plate yield-stress instrument [De Kee et al. (1980)] were minimized by opening a series of slots on the plates. Yield-stress experiments were conducted on both high-concentration (40, 50, 60, and 70 wt % TiO2) and low-concentration (2, 3, and 5 wt % bentonite) aqueous suspensions. The new setup avoids the disadvantages of the vane instrument, possible secondary flow between the blades as well as a nonuniform stress distribution along a virtual cylindrical surface. Yield stress values of TiO2 suspensions were compared with the values obtained via a variety of other methods, including indirect extrapolation from steady-shear data, vane creep testing. and vane stress-ramp measurements using an SR-5000 rheometer. Very small yield stress (up to similar to 10(-4) Pa) measurements of low-concentration bentonite suspensions (2, 3, and 5 wt %) could be determined only with the slotted-plate device. The vane method could not measure yield stress values of bentonite suspensions of less than 7 wt % concentration. Relaxation tests on high-concentration suspensions indicated that these suspensions may not be purely elastic below yield stress.