화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.19, No.6, 2144-2148, 2001
Ion-implanted photoresist removal using water/carbon dioxide mixtures at elevated temperature and pressure
The ability of water and water/1% carbon dioxide mixtures to remove ion-implanted photoresist from silicon substrates was investigated. Photoresist with implant levels up to 2 X 10(15)/cm(2) of boron and phosphorus were stripped effectively at a temperature of 165 degreesC and a pressure of 58.6 bar (850 psi) by both water and water/carbon dioxide. Removal of photoresist at low implant levels (2 X 10(12)/cm(2)) proceeded rapidly, while samples at higher dose levels (>2 X 10(15)/cm(2)) had a thin carbonized layer at the photoresist surface that inhibited the removal rate. Removal of this carbonized layer required approximately 2 min for water/carbon dioxide and approximately 8 min for water, while complete removal of the remaining photoresist film took less than 30 min for both fluids. Patterned, arsenic-implanted (1 X 10(16)/cm(2)) photoresist layers were removed by water/carbon dioxide at 200 degreesC, 850 psi, 3 ml/min flow rate, and 30 min exposure. Under all conditions investigated, water/carbon dioxide proved more effective than pure water at removing ion-implanted photoresist.