화학공학소재연구정보센터
Catalysis Letters, Vol.64, No.2-4, 129-134, 2000
Rate-determining stage in NOSCR with propane on low-exchanged Cu-ZSM-5 catalyst
The kinetics of the NO SCR with propane has been studied on a low-exchanged Cu-ZSM-5 catalyst. The study of the kinetics of individual reaction stages (2-nitrosopropane isomerization to acetone oxime and reaction of adsorbed acetone oxime with gaseous NO) has shown that the NO reaction with acetone oxime is the rate-determining stage in the whole chain of transformations leading to the formation of molecular nitrogen in the low-temperature region below 300 C-degrees. The kinetic analysis of the reaction has revealed that at the temperatures above 300(degrees)C propane plays a more important role.