In this paper a carbon foil (based on intercalated graphite compounds) manufactured in our laboratory was used as electrode material for polycarbazole deposition, due to the excellent properties of this material. Anodic polymerization of carbazole on the carbon foil was performed. Uniform layers of polycarbazole on the carbon foil were obtained. Atomic force microscopy, X-ray diffraction, and electrochemical measurements were achieved on this composite material.