Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.342, 91-96, 2000
Synthesis of novel iron-sulfur complexes with functional ligands for cluster assembly
Iron-sulfur clusters containing a variety of ligands, [Fe4S4(SR)(4)](2-) (R = 4-C6H4CHO 4-C5H4N, 2-(4-NO2)C5H4N) were prepared as potential constituents for functional assembly. Preparation and structure of a mixed-cluster compound (Me4N)(4)[Fe(SPh)(4)] [Fe4S4(SPh)(4)], involving both rubredoxin and [4Fe-4S] ferredoxin model clusters, are also discussed.