Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.342, 133-138, 2000
Synthesis and magnetic property of adducts of ruthenium(II,III) pivalate with 9,10-anthraquinone
Reaction of tetrakis(pivalato)diruthenium(II,III) cation dimer and 9,10-anthraquinone (aq) gave two kinds of adducts, [{Ru-2(piv)(4)(H2O)}(2)(aq)]-(BF4)(2) (1) (pivH = pivalic acid) and [Ru-2(piv)(4)(aq)](n) (2), depending on the condition. Very weak antiferromagnetic interaction was observed for 1. The X-ray crystal structure of 2 shows an one-dimensional chain structure.