화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.354, 1099-1110, 2000
Transport and mechanical properties of polyaniline -Poly(methyl methacrylate) blends exhibiting low percolation threshold
The electronic transport and the dynamic mechanical behavior of conducting polymers blends are studied as a function of the conducting phase content. Electrical percolation is demonstrated for an ultra low threshold (0.03%), whereas a dramatic increase of the relaxed elastic modulus is observed beyond a higher threshold (0.5%). From the analysis of the thermal dependence of conductivity, and the comparison between mechanical and transport data, an image of the phase segregated morphology is proposed.