Polymer Engineering and Science, Vol.41, No.6, 1038-1048, 2001
Evolution of structure in the softening/melting regime of miscible polymer mixing
Structure development in the softening/melting processing regime is investigated using the model miscible blend poly(styrene-co-acrylonitrile) (SAN)/poly(methyl methacrylate) (PMMA). Feed materials of four different particle sizes are compounded to study their effects upon structure development. Fourier-transform infrared spectroscopy is used to help determine the normalized sample variance, a quantitative measure of mixing. The normalized sample variance is determined both as a function of sample size and as a function of feed particle size in an effort to assess the characteristic size scale(s) present in the blend at short mixing times. Results of these experiments indicate that the distribution of size scales in the softening regime is at least bimodal. Optical examination of pigmented mixtures reveals that this multimodality is due to the operation of the Scott/Macosko sheeting mechanism of morphology development, which was previously shown to be active in immiscible blends. This is contrary to the currently accepted laminar mixing model, which postulates the formation of a striated mixture while ignoring the softening/melting regime.