화학공학소재연구정보센터
Journal of Chemical Physics, Vol.116, No.5, 2213-2218, 2002
Phase transitions in a nematic binary mixture
Our objective was to study mixtures of nematic liquid crystals with dissimilar dielectric anisotropies but similar phase properties. Using light scattering and microscopy, we have established the phase boundaries and transition widths of mixtures of 4'-n-pentyl-4-cyanobiphenyl and 4'-methoxybenzylidene-4-butylaniline. In addition to the isotropic-nematic transition, there is a second induced phase for certain concentrations, which we conclude is an induced smectic B phase. Recent theoretical works provide a model for nematic to induced smectic A transition by combining Flory-Huggins and Maier-Saupe-McMillan theories. From our phase transition data and the application of the above theoretical framework, we conclude that there is a possibility of strong interaction between the two mesogens that produces the smectic B phase.