화학공학소재연구정보센터
Journal of Materials Science, Vol.37, No.4, 737-744, 2002
Sinterability of magnesium silicon nitride powder with yttrium oxide addition coated using the homogeneous precipitation method
The sinterability of magnesium silicon nitride (MgSiN2) powder with yttrium oxide (Y2O3) addition was examined using the hot-pressing technique (31 MPa and N-2 atmosphere) at 1550degreesC for 90 min; the MgSiN2 powder had been coated with 0-4 mass% of Y2O3 addition by a (urea-based) homogeneous precipitation method. Relative densities of the hot-pressed MgSiN2 compacts (ceramics) with and without Y2O3 addition were greater than or equal to99.6% apart for the MgSiN(2)ceramic with 4 mass% Y2O3 addition (98.4%). The thermal conductivities of the MgSiN2 ceramics with 0-1 mass% Y2O3 addition were in the range of 20-21 W . m(-1) . K-1 whilst the Vickers hardness was 19.7 GPa for the pure MgSiN2 ceramic and decreased slightly with Y2O3 addition. Average fracture toughness values were in the range of 1.2-1.6 MPa . m(1/2) with significant trend being noted with regards to the ceramic containing 0.5 mass% of Y2O3. It was concluded that the use of homogeneous precipitation processing resulted in significant advantages regarding the densification, homogeneous microstructure, and fracture toughness despite the amount of Y2O3 addition being as low as 0.5 mass%.