Catalysis Today, Vol.69, No.1-4, 357-363, 2001
Preparation and characterisation aspects of carbon-coated monoliths
Carbon-coated monoliths have been prepared by dipcoating cordierite monoliths in a polymer solution and subsequent carbonisation. Parameters of preparation that were varied were viscosity of the dipcoating solution, carbon precursor and carbonisation temperature. Two different commercial polymers have been used as carbon precursors, Novolac and Furan resins. Also monoliths have been coated with slurry of such resins and a commercial mesoporous activated carbon (CP-97). The features of the final carbon that have been optimised are carbon loading, carbon layer thickness, coverage and mesoporosity. Coverage has been tested by leaching test in acid media. Both coverage and mesoporosity are considerably enhanced when the dipcoating mixture was a slurry of Furan resin and a commercial activated carbon. These features makes carbon-coated monoliths very suitable for their use as catalyst support in three-phase reactions.