International Journal of Heat and Mass Transfer, Vol.44, No.13, 2505-2509, 2001
On the mechanism and kinetics of the transport processes in system with intensive interphase mass transfer. 4. Effect of the interface concentration
A comparative analysis of the non-stationary absorption rate of pure (concentrated) gases in a stagnant liquids has been performed. The results obtained indicate that the rate depends on the equilibrium concentration at the interface. A theoretical relationship has been developed. The: relationship confirms the experimental data and explains the differences between the absorption and desorption rates as well.
Keywords:absorption (desorption) mechanism;mass transfer kinetics;stability;interface concentration effect