Combined experimental flow visualization and temperature measurement are carried out in the present study to explore the buoyancy driven vortex flow patterns in a limiting low Reynolds number mixed convective air flow through a bottom heated horizontal flat duct. In Particular, attention is paid to the flow approaching the natural convection limit (Re = 0) for Re = 1.0 and 2.0 with the Rayleigh number near the critical level for the onset of convection for 1200 less than or equal to Ra less than or equal to 4000. Results front the flow visualization have revealed two unfamiliar vortex flow patterns which were not seen in our earlier study [Int. J. Heat Mass Transfer 44 (4) (2001) 705]. One is characterized by the stable stationary transverse rolls in the duct entry and stable longitudinal rolls in the downstream. Another is in the form of U-rolls. The relations of these two patterns with those reported in the literature from analytical, numerical and experimental studies are discussed. Moreover, stable longitudinal rolls along with nonperiodic traversing waves, and mixed longitudinal and transverse rolls as well as irregular cells which appear in the higher Reynolds number for 3.0 less than or equal to Re less than or equal to 5.0 are also noted here. The temporal and spatial characteristics of the unfamiliar vortex flows are inspected in detail. In addition, the flow formation processes leading to tire two unfamiliar vortex flow structures are also examined carefully. During the flow formation we noted merging of longitudinal and transverse rolls to form U-rolls, splitting of rolls into cells and the reverse process of cell integration into rolls, aside from the generation of the longitudinal and transverse rolls. Finally, a flow regime map is provided to delineate various vortex flow structures observed in this study and in the previous study (cf. the above-mentioned reference) driven by the slightly supercritical and subcritical buoyancies for 1.0 less than or equal to Re less than or equal to 5.0.