화학공학소재연구정보센터
Journal of Chemical Physics, Vol.107, No.16, 6196-6203, 1997
Determination of methyl radical concentrations in a methane air flame by infrared cavity ringdown laser absorption spectroscopy
Infrared cavity ringdown laser absorption spectroscopy (IR-CRLAS) is employed to determine absolute methyl radical concentrations in a 37.5 Torr laminar methane/air flame. IR-CRLAS rovibrational absorption spectra of the v(3) fundamental band system near 3200 cm(-1) are combined with N-2-CARS temperature measurements to obtain methyl radical concentrations as a function of height above the burner surface. These data are compared with flame chemistry simulations under both stoichiometric and rich flame conditions. Issues regarding the applicability of IR-CRLAS for combustion studies are discussed, including the uncertainties present for the specific case of methyl radical. These IR-CRLAS measurements indicate the ability to monitor reactants, intermediates, and products within a narrow spectral window, and, to our knowledge, constitute the first infrared detection of a polyatomic radical in a flame. (C) 1997 American Institute of Physics.