New Fe/Mo/S clusters with MoFe3S3 cuboidal cores similar to the one in the Fe/Mo cofactor of nitrogenase. Synthesis and structural characterization of the (C1(4)-cat)MoFe3S3(PEt3)(2)(CO)(6) and (C1(4)-cat)Mo(O)Fe3S3(PEt3)(3)(CO)(5) clusters