SiCl4-(CH3)2SiCl2, SiCl4-CH3SiCl3, SiCl4-(CH3)3SiCl계의 등온 기액평형에 관한 연구(I)

김철웅; 고재천; 이정민

HWAHAK KONGHAK, Vol.31, No.2, 154-159, April, 1993

Export Citation

SiCl₄-(CH₃)₂SiCl₂, SiCl₄-CH₃SiCl₃, SiCl₄-(CH₃)₃SiCl계의 등온 기액평형에 관한 연구(I)

Isothermal Vapor-Liquid Equilibria of SiCl₄-(CH₃)₂ SiCl₂, SiCl₄-CH₃SiCl₃ and SiCl₄-(CH₃)₃SiCl Systems(I)

김철웅, 고재천, 이정민

초록

50℃의 등온하에서 SiCl₄-Me₂SiCl₂, SiCl₄-MeSiCl₃ 그리고 SiCl₄-Me₃SiCl계의 기액평형 실험은 headspace가 스크로마토그래피에 의한 정지법으로 수행하였다. 각 2성분계 혼합물중 SiCl₄-Me₃SiCl계는 공비혼합물을 나타내었으며, 그 외의 혼합물에서는 공비점이 발견되지 않았다. 얻어진 결과는 Wilson, Van Larr, Margules, NRTL식에 상호 연관시켰다. 이러한 2성분계 메틸염화실란에 대한 실험적인 기액평형 데이터를 분리 조작의 기초 데이터로 제시한다.

Isothermal vapor-liquid equilibria have been determined for SiCl₄-Me₂SiCl₂, SiCl₄-MeSiCl₃ and SiCl₄-Me₃SiCl at 50℃ using headspace gas chromatography as static method. The system SiCl₄-Me₃SiCl forms an azeotropic mixture, while the other two systems did not have the azeotrope. The obtained results were correlated to the Wilson, Van Larr, Margules, NRTL equations. These experimental vapor-liquid equilibrium data for binary systems of methychlorosilanes are presented as the basic data of separation process.

[References]

Lee JM, "Developments of Manufacturing Processes of Trichlorosilane and Silicone," KRICT Report (1991)
SRI Report: "Process Economic Program Report," No. 160, SRI International (1983)
Hurd DT, Rochow EG, J. Am. Chem. Soc., 67, 1057 (1945)
Rochow EG, Schenectady NY, U.S. Patent, 2,380,995 (1945)
Petrov P, Genkova P, Vysokochist. Veshchestva, 4, 74 (1990)
Trandafir R, Liviu S, Mariana G, Revista de Chimie, 39, 869 (1988)
Trandafir R, Liviu S, J. Chem. Eng. Data, 37, 143 (1992)
Nagata I, Ohta T, J. Chem. Eng. Jpn., 5, 3 (1972)
Walas SM, "Phase Equilibria in Chemical Engineering," Butterworth Publishers (1985)
Loffe BV, Vitenberg AG, "Headspace Analysis & Related Methods in Gas Chromatography," John Wiley & Sons (1984)
Park SJ, Choi BH, Rhee BS, HWAHAK KONGHAK, 25(5), 512 (1987)
Park SJ, Rhee BS, HWAHAK KONGHAK, 28(4), 386 (1990)
Weast RC, Astle MJ, Beyer WH, "CRC Handbook of Chemistry and Physics," 65, CRC Press (1984)
Dena JA, Lange NA, "Lange's Handbook of Chemistry," 13, McGraw-Hill, New York (1985)
Gmehling J, Onken U, Arlt W, "Vapor-Liquid Equilibrium Data Collection," (1977)
The Chemshare Corporation: "Design II User's Guide," (1985)
John K, "SigmaPlot 4.1 Beginner's Guide," 18 (1989)

[Referenced By]

[1] Lee JM, "Developments of Manufacturing Processes of Trichlorosilane and Silicone," KRICT Report (1991)

[2] SRI Report: "Process Economic Program Report," No. 160, SRI International (1983)

[3] Hurd DT, Rochow EG, J. Am. Chem. Soc., 67, 1057 (1945)

[4] Rochow EG, Schenectady NY, U.S. Patent, 2,380,995 (1945)

[5] Petrov P, Genkova P, Vysokochist. Veshchestva, 4, 74 (1990)

[6] Trandafir R, Liviu S, Mariana G, Revista de Chimie, 39, 869 (1988)

[7] Trandafir R, Liviu S, J. Chem. Eng. Data, 37, 143 (1992)

[8] Nagata I, Ohta T, J. Chem. Eng. Jpn., 5, 3 (1972)

[9] Walas SM, "Phase Equilibria in Chemical Engineering," Butterworth Publishers (1985)

[10] Loffe BV, Vitenberg AG, "Headspace Analysis & Related Methods in Gas Chromatography," John Wiley & Sons (1984)

[11] Park SJ, Choi BH, Rhee BS, HWAHAK KONGHAK, 25(5), 512 (1987)

[12] Park SJ, Rhee BS, HWAHAK KONGHAK, 28(4), 386 (1990)

[13] Weast RC, Astle MJ, Beyer WH, "CRC Handbook of Chemistry and Physics," 65, CRC Press (1984)

[14] Dena JA, Lange NA, "Lange's Handbook of Chemistry," 13, McGraw-Hill, New York (1985)

[15] Gmehling J, Onken U, Arlt W, "Vapor-Liquid Equilibrium Data Collection," (1977)

[16] The Chemshare Corporation: "Design II User's Guide," (1985)

[17] John K, "SigmaPlot 4.1 Beginner's Guide," 18 (1989)