Journal of Colloid and Interface Science, Vol.163, No.2, 372-378, 1994
THE SEEDED GROWTH OF CALCIUM-SULFATE DIHYDRATE CRYSTALS IN NACL SOLUTIONS UP TO 6-M AND 90-DEGREES-C
The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90-degrees-C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO4-H2O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was similar to the crystal solubility behavior in aqueous electrolyte solutions resulting from the variation of the mean activity coefficient of the crystal with ionic strength. The rate constant is proportional to the crystal solubility and inversely proportional to the edge work or the interfacial tension as expected in the classic BCF model. (C) 1994 Academic Press. Inc.