In this study, the role of lanthanide elements (Ce, Gd, La, and Yb) on Pd/TiO2 catalysts in the catalytic reduction of NO with methane was investigated. Steady-state reaction experiments in the presence of oxygen showed that the addition of lanthanide elements increases the oxygen resistance of the catalyst. The post-reaction XPS characterization results revealed that majority of the Pd sites remained in the zero oxidation state in the presence of Ce or Gd. The effect of SO2 (145 ppm) and H2O (0-6.6%) in NO-CH4-O-2 reaction over supported Pd and Gd-Pd catalysts was also investigated. Over the Gd-Pd catalyst with the presence of SO2, more than 70% NO conversion was obtained for over 6 h while the Pd only catalyst showed a sharper drop in NO conversion. Over the Gd-Pd catalyst, the presence of H2O showed no effect on NO conversion activity (>99% conversion) during the 18 h the catalyst was kept on stream. Among the lanthanide elements tested, Gd is the most effective, allowing the use of above stoichiometric oxygen concentration.