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Fluid Phase Equilibria, Vol.167, No.2, 263-284, 2000
Solubility of hydrogen sulfide in aqueous solutions of single strong electrolytes sodium nitrate, ammonium nitrate, and sodium hydroxide at temperatures from 313 to 393 K and total pressures up to 10 MPa
New experimental results for the solubility of hydrogen sulfide in aqueous solutions of the single strong electrolytes sodium nitrate, ammonium nitrate, and sodium hydroxide at temperatures from 313 to 393 K and total pressures up to 10 MPa are reported. As in the strong electrolyte-free system, a second -hydrogen sulfide-rich - liquid phase is observed at high hydrogen sulfide concentrations. A thermodynamic model for describing the phase equilibrium is presented. Calculations are compared with the new experimental data.
Keywords:gas solubility;experimental data;vapor-liquid equilibrium;aqueous solutions;electrolytes;hydrogen sulfide;sodium nitrate;ammonium nitrate;sodium hydroxide