Rotational molding involves powder mixing, heating and melting of powder particles to form a homogeneous polymer melt, as well as cooling and solidification. The densification. of a loose powder compact into a homogeneous melt occurs over a wide range of conditions as the material passes from a solid state into a melt state. The numerical simulation of the non-isothermal melt densification in the rotational molding process is presented in this work. The simulation combines heat transfer, polymer sintering and bubble dissolution models, and is based on an idealized packing arrangement of powder particles. The predictions are in general agreement with experimental observations presented in the literature for the rotational molding of polyethylenes. The simulation allows for systematic and quantitative studies on the effect of molding conditions and material properties on the molding cycle and molded part density. Results indicate that the densification process is primarily affected by the powder characteristics, which are accounted for in terms of the particle size and the particle packing arrangement. The material rheological. properties become increasingly important as the powder characteristics lessen in quality. The simulation demonstrated that while certain combinations of processing conditions help reduce the molding cycle, they have a detrimental effect on the densification process.