Chemical Ripening of AgBr Octahedral Microcrystals

Myung Cheon Lee; Jong Choo Lim; Euy Soo Lee; Hong C. Ahn; N.S. Zvidentsova; L.V. Kolesnikov; I.L. Kolesnikova

Journal of Industrial and Engineering Chemistry, Vol.8, No.3, 247-252, May, 2002

Myung Cheon Lee^†, Jong Choo Lim , Euy Soo Lee , Hong C. Ahn¹, N.S. Zvidentsova², L.V. Kolesnikov², and I.L. Kolesnikova²

Department of Chemical Engineering, Dongguk University, Seoul 100-715, Korea
¹Korea Research Institute of Chemical Technology, Daejeon, Korea
²Kemerovo State University, Kemerovi, Russian Federation

E-mail:

The results of the chemical sensitization study of octahedral AgBr microcrystals with the sizes 0.75 - 1.3 μm in various modes of ripening are presented. Spontaneous sensitization (thermal ripening of emulsions without photographically active additives) has been investigated. The spontaneous sensitization is effected regardless of the type of gelatins during synthesis and chemical sensitization. The influence of both the pBr value of chemical ripening and the adsorption of stabilizers and gold ions on photographic characteristics of emulsions in modes of spontaneous and sulfur sensitization have been studied. The data obtained are compared with the results of the similar investigations carried out with the emulsions containing cubic microcrystals, as well as tabular microcrystals. The peculiarities of photosensitivity centre formation in AgBr (111) microcrystals are discussed in terms of ionic conductivity change during chemical ripening.

Keywords:ripening;microcrystals;AgBr;photosensitivity

[References]

Moisar E, J. Photogr. Sci., 16, 102 (1968)
Takada S, J. Soc. Photogr. Sci. Tech. Jpn., 44, 81 (1981)
Tamura M, Hada H, Naguchi J, J. Phys. Chem., 66, 559 (1962)
Callens F, Vost W, Photogr. Sci. Eng., 27, 202 (1983)
Van Biesen J, J. Appl. Phys., 41, 1910 (1970)
Ohzeki K, Urabe S, Tani T, J. Imag. Sci., 34, 136 (1990)
Kolesnikov LV, Sergeeva IA, Svistunova VV, Proceeding of IS&T's 47th Annual Conf., Rochester, Vol. 1, p. 221, New York (1994)
Tani T, Photogr. Sci. Eng., 21, 318 (1977)
Kolesnikov LV, Sergeeva IA, Zh. Techn. Phys., 64, 184 (1994)
Spenser HE, Levi M, J. Soc. Photogr. Sci. Technol. Jpn., 46, 514 (1983)
Takiguchi H, J. Soc. Photogr. Sci. Technol. Jpn., 48, 424 (1985)
Takiguchi H, J. Imag. Sci., 32, 20 (1988)
Shiao DDF, Nieh MT, Herz AH, J. Photogr. Sci., 30, 208 (1982)
Harenburg J, Israel G, Siegal J, Proceeding of IS&T's 49th Annual Conf., Minneapolis, p. 229 (1996)
Kolesnikov LV, Mikhailova IV, Zvidentsova NS, Sergeeva IA, Proceeding of IS&T's 48th Annual Conf., Washington, p. 287 (1995)
Kolesnikova IL, Zvidentsova NS, Sozinov SA, Proceeding of IS&T's 53th Annual Conf., Canada, Quebec, p. 148 (2000)
Van Doorseler MK, J. Imag. Sci. Technol., 91, 524 (1993)
Sugimito T, J. Colloid Interface Sci., 91, 51 (1983)
Tani T, Saito M, Photogr. Sci. Eng., 23, 323 (1979)
Tani T, Photogr. Sci. Eng., 25, 236 (1981)
Wood HW, J. Phot. Sci., 14, 72 (1966)
Jun PZ, Ping C, Li QS, De SZ, J. Phot. Sci., 44, 58 (1996)
Pouradier J, Pailliotet A, J. Photogr. Sci., 29, 83 (1981)
Cash DJ, Ferguson AN, J. Photogr. Sci., 28, 121 (1980)
Smith DL, Luss HR, Photogr. Sci. Eng., 20, 184 (1976)
Tani T, Photogr. Sci. Eng., 21, 37 (1977)

[Referenced By]

[Related Articles]

[1] Moisar E, J. Photogr. Sci., 16, 102 (1968)

[2] Takada S, J. Soc. Photogr. Sci. Tech. Jpn., 44, 81 (1981)

[3] Tamura M, Hada H, Naguchi J, J. Phys. Chem., 66, 559 (1962)

[4] Callens F, Vost W, Photogr. Sci. Eng., 27, 202 (1983)

[5] Van Biesen J, J. Appl. Phys., 41, 1910 (1970)

[6] Ohzeki K, Urabe S, Tani T, J. Imag. Sci., 34, 136 (1990)

[7] Kolesnikov LV, Sergeeva IA, Svistunova VV, Proceeding of IS&T's 47th Annual Conf., Rochester, Vol. 1, p. 221, New York (1994)

[8] Tani T, Photogr. Sci. Eng., 21, 318 (1977)

[9] Kolesnikov LV, Sergeeva IA, Zh. Techn. Phys., 64, 184 (1994)

[10] Spenser HE, Levi M, J. Soc. Photogr. Sci. Technol. Jpn., 46, 514 (1983)

[11] Takiguchi H, J. Soc. Photogr. Sci. Technol. Jpn., 48, 424 (1985)

[12] Takiguchi H, J. Imag. Sci., 32, 20 (1988)

[13] Shiao DDF, Nieh MT, Herz AH, J. Photogr. Sci., 30, 208 (1982)

[14] Harenburg J, Israel G, Siegal J, Proceeding of IS&T's 49th Annual Conf., Minneapolis, p. 229 (1996)

[15] Kolesnikov LV, Mikhailova IV, Zvidentsova NS, Sergeeva IA, Proceeding of IS&T's 48th Annual Conf., Washington, p. 287 (1995)

[16] Kolesnikova IL, Zvidentsova NS, Sozinov SA, Proceeding of IS&T's 53th Annual Conf., Canada, Quebec, p. 148 (2000)

[17] Van Doorseler MK, J. Imag. Sci. Technol., 91, 524 (1993)

[18] Sugimito T, J. Colloid Interface Sci., 91, 51 (1983)

[19] Tani T, Saito M, Photogr. Sci. Eng., 23, 323 (1979)

[20] Tani T, Photogr. Sci. Eng., 25, 236 (1981)

[21] Wood HW, J. Phot. Sci., 14, 72 (1966)

[22] Jun PZ, Ping C, Li QS, De SZ, J. Phot. Sci., 44, 58 (1996)

[23] Pouradier J, Pailliotet A, J. Photogr. Sci., 29, 83 (1981)

[24] Cash DJ, Ferguson AN, J. Photogr. Sci., 28, 121 (1980)

[25] Smith DL, Luss HR, Photogr. Sci. Eng., 20, 184 (1976)

[26] Tani T, Photogr. Sci. Eng., 21, 37 (1977)