Korean Journal of Chemical Engineering, Vol.19, No.3, 486-490, May, 2002
Dry Etching of SrBi2Ta2O9: Comparison of Inductively Coupled Plasma Chemistries
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A systematic study of the etch characteristics of SrBi2Ta2O9 (SBT) thin films in inductively coupled plasmas (ICPs) has been performed with various chemistries of Cl2/Ar, Cl2/O2/Ar, Cl2/NF3/Ar, and Cl2/NF3/O2/Ar. Etch rate was dependent on plasma chemistries and parameters. Addition of O2 stabilized the perovskite structure of SBT film and suppressed the etch rate, but NF3 enhanced the etch rate substantially mainly due to reactive fluorine radicals. Maximum etch rates obtained were: 740 Å/min with Cl2/Ar, 320 Å/min with Cl2/O2/Ar, 1,500 Å/min with Cl2/NF3/Ar, and 1,600 Å/min with Cl2/NF3/O2/Ar at 5 mTorr, 700W ICP power and 150 W rf chuck power. Electrical properties of the SBT films were quite dependent on plasma chemistries employed; Cl2/NF3/O2/Ar showed the least damage in the films and resulted in the best P-E hysteresis loop having remnant polarization (2Pr)=12.3 μC/cm(2) and coercive field (Ec)=41.9 V/cm.
- Bu SD, Park BH, Kang BS, Kang SH, Noh TW, J. Korean Phys. Soc., 35, S1197 (1999)
- Desu SB, Pan W, Appl. Phys. Lett., 68, 566 (1996)
- Zhang WJ, Sun C, Bello I, Lee CS, Lee ST, J. Vac. Sci. Technol. A, 17(3), 763 (1999)
- Hahn YB, Pearton SJ, Korean J. Chem. Eng., 17(3), 304 (2000)
- Hahn YB, Hays DC, Cho H, Jung KB, Abernathy CR, Donovan SM, Pearton SJ, Han J, Shul RJ, Mat. Sci. Eng. B, 60, 95 (1999)
- Hahn YB, Hays DC, Cho H, Jung KB, Abernathy CR, Pearton SJ, Appl. Surf. Sci., 147(1-4), 207 (1999)
- Hahn YB, Hays DC, Cho H, Jung KB, Abernathy CR, Peartn SJ, Appl. Surf. Sci., 147(1-4), 215 (1999)
- Hays DC, Cho H, Jung KB, Hahn YB, Abernathy CR, Pearton SJ, Appl. Surf. Sci., 147(1-4), 134 (1999)
- Im YH, Park JS, Choi CS, Choi RJ, Hahn YB, Lee SH, Lee JK, J. Vac. Sci. Technol. A, 19(4), 1315 (2001)
- Lee JK, Jung HJ, Auciello O, Kingon AI, J. Vac. Sci. Technol. A, 14(3), 900 (1996)
- Lee JS, Kwon HJ, Jeong YW, Kim HH, Hyun SJ, Noh TW, Appl. Phys. Lett., 74, 2690 (1999)
- Lee WJ, Cho CR, Kim SH, You IK, Kim BW, Yu BG, Shin CH, Lee HC, Jpn. J. Appl. Phys., 38(2), L1428 (1999)
- Lieberman MA, Lichtenberg JA, "Principles of Plasma Discharges and Materials Processing," John-Wiley and Sons, Inc., N.Y. (1994)
- Park BH, Kang BS, Bu SD, Noh TW, Lee J, Jo W, Nature, 401, 682 (1999)