A Study of Electrochemical Kinetics of Lithium Ion in Organic Electrolytes

Shung-Ik Lee; Un-Ho Jung; Yun-Sung Kim; Myung-Hwan Kim; Dong-June Ahn; Hai-Soo Chun

Korean Journal of Chemical Engineering, Vol.19, No.4, 638-644, July, 2002

DOI10.1007/BF02699310 Export Citation

A Study of Electrochemical Kinetics of Lithium Ion in Organic Electrolytes

Shung-Ik Lee, Un-Ho Jung, Yun-Sung Kim, Myung-Hwan Kim¹, Dong-June Ahn , and Hai-Soo Chun^†

Department of Chemical Engineering, Korea University, Seoul 136-701, Korea
¹Battery Research Institute, LG Chem. Ltd., Daejeon 305-380, Korea

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Limiting current densities equivalent to the transport-controlling step of lithium ions in organic electrolytes were measured by using a rotating disk electrode (RDE). The diffusion coefficients of lithium ion in the electrolyte of PC/LiClO4, EC : DEC/LiPF6 and EC : DMC/LiPF6 were determined by the limiting current density data according to the Levich equation. The diffusion coefficients increased in the order of PC/LiClO4

Keywords:Lithium Ion Batteries;RDE;Electrolyte;Limiting Current Density;Diffusion Coefficient

[References]

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Aurbach D, Markovsky B, Shechter A, Eineli Y, Cohen H, J. Electrochem. Soc., 143(12), 3809 (1996)
Blint RJ, J. Electrochem. Soc., 144(3), 787 (1997)
Blomgren GE, "Lithium Batteries," (ed. by Gabano J.P.) Chap. 2, Academic Press Inc. (London) Ltd. (1993)
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Cazzanelli E, Croce F, Appetecchi GB, Benevelli F, Mustarelli P, J. Chem. Phys., 107(15), 5740 (1997)
Cussler EL, "Diffusion, Mass Transfer in Fluid Systems," Cambridge Univ. Press, 118 (1984)
Dominey LA, "Lithium Batteries, New Materials, Developments and Perspectives, Industrial Chemistry Liblary," (Edited by G. Pistoia) Vol. 5, Chap. 4, Elsevier Amsterdam (1994)
Eineli Y, Thomas SR, Koch VR, J. Electrochem. Soc., 143(9), L195 (1996)
Eineli Y, Thomas SR, Chadha R, Blakley TJ, Koch VR, J. Electrochem. Soc., 144(3), 823 (1997)
Horvath AL, "Handbook of Aqueous Electrolyte Solutions," Ellis Horwood Limited, New York (1985)
Ishikawa M, Morita M, Asao M, Matsuda Y, J. Electrochem. Soc., 141(5), 1105 (1994)
Jung UH, Lee SI, Chun HS, Lee HH, Lee KY, Kim MH, "Electrochemical Characteristics of Electrolytes for Lithium Ion Battery," Proceeding of Korean Electrochemical Society, Seoul, Korea, Oct., 141 (1998)
Kanamura K, Takezawa H, Shiraishi S, Takehara Z, J. Electrochem. Soc., 144(6), 1900 (1997)
Langenhuizen NPW, J. Electrochem. Soc., 145(9), 3094 (1998)
Lee SI, Lee JS, Park JH, Park GP, Lim JH, Lee JK, Chun HS, HWAHAK KONGHAK, 38(2), 129 (2000)
Matsuda Y, Morita M, Tachihara F, Bull. Chem. Soc. Jpn., 59, 1967 (1986)
Nam SC, Lim YC, Park HY, Jeon EJ, Yoon YS, Cho WI, Cho BW, Yun KS, Korean J. Chem. Eng., 18(5), 673 (2001)
Naoi K, Mori M, Shinagawa Y, J. Electrochem. Soc., 143(8), 2517 (1996)
Quickenden TI, Jiang X, Electrochim. Acta, 29, 639 (1984)
Uceda DA, O'Keefe TJ, Cole ER, J. Electrochem. Soc., 137, 1397 (1990)
Verbrugge MW, Koch BJ, J. Electrochem. Soc., 141(11), 3053 (1994)
Wang X, Iyoda M, Nishida T, Uchida I, "Application of Microelectrode Technique to Kinetic Study of the Lithium Deposition/Dissolutionand Alloying in Organic Solution," Ext. Abstracts of 8th International Meeting on Lithium Batteries, Nagoya, Japan, 16-21, June, 385 (1996)
Zhang SS, Angell CA, J. Electrochem. Soc., 143(12), 4047 (1996)

[Related Articles]

[1] Aurbach D, Zaban A, Gofer Y, Ein-Eli Y, Weissman I, Chusid O, Abramson O, J. Power Sources, 54, 76 (1995)

[2] Aurbach D, Markovsky B, Shechter A, Eineli Y, Cohen H, J. Electrochem. Soc., 143(12), 3809 (1996)

[3] Blint RJ, J. Electrochem. Soc., 144(3), 787 (1997)

[4] Blomgren GE, "Lithium Batteries," (ed. by Gabano J.P.) Chap. 2, Academic Press Inc. (London) Ltd. (1993)

[5] Bockris J, Reddy A, "Modern Electrochemistry," Plenum Press, New York (1973)

[6] Cazzanelli E, Croce F, Appetecchi GB, Benevelli F, Mustarelli P, J. Chem. Phys., 107(15), 5740 (1997)

[7] Cussler EL, "Diffusion, Mass Transfer in Fluid Systems," Cambridge Univ. Press, 118 (1984)

[8] Dominey LA, "Lithium Batteries, New Materials, Developments and Perspectives, Industrial Chemistry Liblary," (Edited by G. Pistoia) Vol. 5, Chap. 4, Elsevier Amsterdam (1994)

[9] Eineli Y, Thomas SR, Koch VR, J. Electrochem. Soc., 143(9), L195 (1996)

[10] Eineli Y, Thomas SR, Chadha R, Blakley TJ, Koch VR, J. Electrochem. Soc., 144(3), 823 (1997)

[11] Horvath AL, "Handbook of Aqueous Electrolyte Solutions," Ellis Horwood Limited, New York (1985)

[12] Ishikawa M, Morita M, Asao M, Matsuda Y, J. Electrochem. Soc., 141(5), 1105 (1994)

[13] Jung UH, Lee SI, Chun HS, Lee HH, Lee KY, Kim MH, "Electrochemical Characteristics of Electrolytes for Lithium Ion Battery," Proceeding of Korean Electrochemical Society, Seoul, Korea, Oct., 141 (1998)

[14] Kanamura K, Takezawa H, Shiraishi S, Takehara Z, J. Electrochem. Soc., 144(6), 1900 (1997)

[15] Langenhuizen NPW, J. Electrochem. Soc., 145(9), 3094 (1998)

[16] Lee SI, Lee JS, Park JH, Park GP, Lim JH, Lee JK, Chun HS, HWAHAK KONGHAK, 38(2), 129 (2000)

[17] Matsuda Y, Morita M, Tachihara F, Bull. Chem. Soc. Jpn., 59, 1967 (1986)

[18] Nam SC, Lim YC, Park HY, Jeon EJ, Yoon YS, Cho WI, Cho BW, Yun KS, Korean J. Chem. Eng., 18(5), 673 (2001)

[19] Naoi K, Mori M, Shinagawa Y, J. Electrochem. Soc., 143(8), 2517 (1996)

[20] Quickenden TI, Jiang X, Electrochim. Acta, 29, 639 (1984)

[21] Uceda DA, O'Keefe TJ, Cole ER, J. Electrochem. Soc., 137, 1397 (1990)

[22] Verbrugge MW, Koch BJ, J. Electrochem. Soc., 141(11), 3053 (1994)

[23] Wang X, Iyoda M, Nishida T, Uchida I, "Application of Microelectrode Technique to Kinetic Study of the Lithium Deposition/Dissolutionand Alloying in Organic Solution," Ext. Abstracts of 8th International Meeting on Lithium Batteries, Nagoya, Japan, 16-21, June, 385 (1996)

[24] Zhang SS, Angell CA, J. Electrochem. Soc., 143(12), 4047 (1996)