Polyethylene-g-polyacrylamide membranes were prepared by graft polymerization of acrylamide into polyethylene films using a preirradiation technique. The membranes showed good swelling in water and a maximum of 232%, swelling was achieved for a graft level of 590%. The electrical resistance of the membranes decreased with increase in the degree of grafting to 200% and then stabilized with a further increase in grafting to 590%.. The membranes had an excellent binding capacity for mercury ions. Almost 99% mercury separation was achieved from a metal solution of 200 ppm. The metal binding capacity increased with increase in the degree of grafting in the membranes. A binding capacity as high as 6.2 mmol/g in a membrane with 590% grafting was achieved. The pH of the metal solution did not have any significant influence on the binding ability of the membranes. The mercury-loaded membranes showed better thermal stability as compared to those without metal binding.