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Journal of Applied Polymer Science, Vol.85, No.2, 438-453, 2002
Mechanical and morphological properties of white rice husk ash filled polypropylene/ethylene-propylene-diene terpolymer thermoplastic elastomer composites
The performance of white rice husk ash (WRHA) as filler for polypropylene (PP)/ethylene-propylene-diene terpolymer (EPDM) thermoplastic elastomer (TPE) composites was investigated. The composites with different filler loadings were prepared in a Brabender plasticorder internal mixer. Both unvulcanized and dynamically vulcanized composites were prepared. Mixing and vulcanization processes of the composites were monitored through the typical Brabender torque-time curves. The mechanical properties and morphology of the composites were also studied. The Brabender torque curves revealed that the dynamic Vulcanization process employed was successful and incorporation of filler has no adverse effect on the processibility of the composites. Incorporation of WRHA improves the tensile modulus and flexural modulus and lowers tensile strength, elongation at break, tear strength, and toughness of both types of composites. Dynamic vulcanization significantly enhances the mechanical and TPE properties of the composites. Dynamic mechanical analysis (DNLA) study revealed the existence of two phases in both types of composites. It further shows that neither dynamic vulcanization nor filler agglomeration has played a prominent role in the compatibility of the composites. Thermogravimetric investigation shows that dynamic vulcanization or WRHA loading has not adversely affected the thermal stability of the composites. The scanning electron micrographs provide evidence for the tendency to form filler agglomerates with increasing filler loading, better filler dispersion of dynamically vulcanized composites over unvulcanized composites, and effective vulcanization of elastomer phase of the composites in the presence of filler.
Keywords:mechanical properties;morphology;thermoplastic elastomer composites;white rice husk ash;ethylene-propylene-diene terpolymer;polypropylene;dynamic vulcanization