The experimental charge density of a highly substituted fullerene derivative, the T-h-symmetrical dodekakis-(ethoxycarbonyl)-C-60-fullerene cocrystallized with difluorobenzene, C102H60O24.2C(6)H(4)F(2), was determined, on the basis of a high-resolution synchrotron/CCD data set of more than 350 000 reflections. A full topological analysis, using Bader's AIM theory, was performed., Experimental bond critical point (BCP) properties, obtained by three multipole models, were compared to each other and, to those derived by theoretical methods from,HF/6-31G** and from B3LYP/6-31G** calculations. rho(r(BCP)) vs bond distance relationships were investigated for the different experimental and theoretical models. Based, on linear fits obtained for experimental model densities,: rho(r(BCP)) values of further C-C bonds can be predicted. One to substitution, this C-60 derivative has six chemically different C-C bonds. A statistical analysis of the BCP properties for these bonds was carried out to explore the reproducibility of different topological descriptors.