Journal of Chemical Physics, Vol.117, No.8, 3583-3596, 2002
Rotational Brownian motion of a pair of linear molecules or dipoles with anisotropic interaction
The rotational Smoluchowski equation for the orientational distribution function of two identical linear molecules or dipoles with anisotropic interaction is solved by expansion in terms of a limited set of eigenfunctions of the operator for free rotational diffusion. The equilibrium self-correlation and pair time-correlation functions of the two axial unit vectors or dipole moments are evaluated for the special case of electrostatic or magnetostatic dipole interaction. The interactions appreciably influence the relaxation behavior.