화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.8, No.5, 432-436, September, 2002
Bed-Shrinking Flow-Through Reactor in Dilute Acid Hydrolysis of Cane Bagasse Cellulose
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The kinetics of cellulose hydrolysis under dilute acid conditions (1.0, 2.0, and 3.0 wt.%), including extremely low acid (ELA) conditions (0.07 wt.%) and a temperature range of 180-220 ℃ were investigated using batch reactors and bed-shrinking flow-through (BSFT) reactors. The maximum yield of glucose obtained from the batch reactor experiments is about 30% from sugarcane bagasee which occurred at 200 and 210 ℃. The maximum glucose yields from pre-treated bagasse feedstocks based on a BSFT reaction increased to 55%. With sugarcane bagasse feedstocks, a large amount of glucose is unaccounted for in the latter phase of batch reactions. Therefore, to improve the BSFT reactor performance, a two-stage BSFT reaction was applied using hydrogen peroxide. It appears that a half amount of K. lignin was released during the first-stage reaction, while the maximum glucose yield increased through the second-stage BSFT reaction. The maximum yield of glucan hydrolysis using the two-stage BSFT reaction under ELA conditions at a high reaction temperature was much higher than that from the batch and BSFT reactions. In the experiments using a two-stage BSFT reaction, a glucose yield of 63% was obtained for sugarcane bagasse feedstocks at respective temperatures of 210 and 220 ℃ under ELA conditions.
  1. Faith WL, Ind. Eng. Chem., 37(1), 9 (1945) 
  2. Thompson DP, Grethlein HE, Ind. Eng. Chem. Prod. Res. Dev., 18(3), 166 (1979)
  3. Oh KK, Kim YS, Yoon HH, Tae BS, J. Ind. Eng. Chem., 8(1), 64 (2002)
  4. Cahelar DR, Lee YY, Chambers RP, Biotechnol. Bioeng., 25, 3 (1979)
  5. Song SK, Lee YY, Chem. Eng. Commun., 17, 23 (1983)
  6. Torget RW, Kim JS, Lee YY, Ind. Eng. Chem. Res., 39(8), 2817 (2000)
  7. Kim JS, Lee YY, Torget RW, Appl. Biochem. Biotechnol., 91-93, 331 (2001)
  8. Grohmann K, Himmel ME, Rivard C, Tucker M, Baker J, Torget RW, Biotechnol. Bioeng. Symp., 14, 137 (1984)
  9. Vinzant TB, Ponfick L, Nagle NJ, Ehrman CI, Reynolds JB, Himmel ME, Appl. Biochem. Biotechnol., 45-46, 611 (1994)
  10. Chen RF, Wu ZW, Lee YY, Appl. Biochem. Biotechnol., 70-72, 37 (1998)