Chinese Journal of Chemical Engineering, Vol.10, No.2, 212-217, 2002
Lumped time distribution function of dynamic equilibrium system and its application in calculating molecular weight distribution of polymer
The lumped time distribution functions were proposed, which can be used for describing the dynamic systems with two or more than two states of the end of growing polymer chain during chain addition polymerization. Numerical analysis of the lumped time distribution functions was carried out. The method for calculating molecular weight distribution of polymer in the stable free radical polymerization and more general cases was developed based on the lumped time distribution functions.