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Fluid Phase Equilibria, Vol.198, No.1, 1-14, 2002
(Solid plus liquid) phase equilibria of binary mixtures containing N-methyl-2-pyrrolidinone and long-chain n-alkanols at atmospheric pressure
The (solid + liquid) equilibria for N-methyl-2-pyrrolidinone + n-alkanols (1-hexanol, or 1-heptanol, or 1-octanol, or 1-decanol, or 1-undecanol, or 1-dodecanol, or 1-tetradecanol) systems have been measured by a dynamic method for the whole concentration region x(1) = 0-1. The experimental results have been correlated by four equations: Wilson, UNIQUAC ASM and two modified NRTL. The relative standard deviations of the solubility temperature correlation for all measured data vary from 0.1 to 1.4 K and depend on the particular equation used. In the calculations, the existence of two solid-solid first-order phase transitions in 1-tetradecanol has been taken into consideration.
Keywords:experimental;solid-liquid equilibria;NMP;1-alkanols;correlation;Wilson;UNIQUAC ASM;NRTL1;NRTL2