This work demonstrates that an increase in soluble silicate concentration over similar to200 mM in an aqueous alkaline solution (pH = similar to13.95) can significantly increase the reactivity of a Class F fly ash at room temperature. The greatly increased dissolution of the fly ash primary phase(s) and the subsequent secondary precipitation are responsible for the formation of an aluminosilicate gel similar to the major binding phase of a geopolymer. On the basis of this observation, a reaction model was developed to simulate aluminosilicate gel formation in a real geopolymeric system. In this work, potassium salts of chloride, carbonate, oxalate, and phosphate (KCl, K2CO3, K2C2O4.H2O, and K2HPO4) were used as solution contaminants. It was found that the anions (Cl-, CO32-, C2O42-, and PO43-) significantly affected the formation kinetics as well as the nature of the aluminosilicate gel formed in the reaction model. This observation could be successfully used to mechanistically explain the retardation effects of the various salts on the gel solidification time of a geopolymer. Aluminosilicate crystallization in the chloride-affected and the oxalate-affected reaction models implies that similar processes could also occur in geopolymers. This could affect the chemical stability and durability of geopolymers and thoroughly deserves a careful future investigation.