The preparation of fullerene complexes with metal tetraarylporphyrins in the presence of excess ferrocene (Cp2Fe) results in the formation of new solvent-free and multicomponent molecular crystals. New isomorphous complexes Of C-60 with PyZnTPP (ZnTPP equivalent to zinc 5,10,15,20-tetraphenyl-21H,23H-porphyrinate) and PyCoTPP (CoTPP equivalent to cobalt(II) 5,10,15,20-tetraphenyl-21H,23H-porphyrinate) containing Cp2Fe and the isostructural C-70 complex with PyZnTPP have been prepared. The crystal structures of the new layered C60 complexes CoTMPP.C-60 (obtained in the presence Of CP2Fe) and CoTMPP.2C(60).3C(7)H(8) (obtained in the absence Of Cp2Fe) have been described (CoTMPP equivalent to cobalt(II) 5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate). Cobalt atoms of the PyCoTPP and CoTMPP molecules are weakly coordinated to C-60 with CO...C(C-60) distances in the 2.64-2.82 Angstrom range, whereas zinc atoms of PyZnTPP, as well as cobalt atoms of the CoTMPP molecules in the solvent-free phase, form only van der Waals contacts with fullerenes. Different packing arrangements in the crystals of fullerene-porphyrin complexes have been discussed.