화학공학소재연구정보센터
Journal of Chemical Physics, Vol.117, No.13, 6281-6288, 2002
Dielectric spectroscopy on the plastically crystalline phase of cyanocyclohexane
Dielectric measurements (10(-2)-10(9) Hz) on plastically crystalline cyanocyclohexane reveal a glass transition where the rotational dynamics freezes at a vitrification temperature T-g=134 K. A full line-shape analysis of the dielectric loss spectra, which include a pronounced secondary relaxation contribution (beta process) in addition to the main relaxation, is performed. We show that the rotational dynamics in cyanocyclohexane is very similar to that of supercooled liquids. In particular the secondary process of cyanocyclohexane exhibits the features characteristic of the Johari-Goldstein beta relaxation known from structural glass formers.