Journal of Chemical Thermodynamics, Vol.34, No.6, 861-873, 2002
Partial molar volumes of organic solutes in water. VII. o- and p-aminobenzoic acids at T=298 K to 498 K and o-diaminobenzene at T=298 K to 573 K and pressures up to 30 MPa
Density data for dilute aqueous solutions of two isomeric aminobenzoic acids and of o-diaminobenzene (1,2-diaminobenzene) are presented together with partial molar volumes calculated from the experimental data. The measurements were performed at temperatures from 298.15 K up to either 498.15 K (aminobenzoic acids) or 573.15 K (o-diaminobenzene) and at either atmospheric pressure, or at pressures close to the saturated vapour pressure of water, and also at pressure p = 30 MPa. The data were obtained using either a high-temperature and high-pressure flow vibrating-tube densimeter for measurements at elevated pressures or a commercial vibrating-tube cell DMA 602HT for measurements at atmospheric pressure.
Keywords:density;partial molar volume;aqueous aminobenzoic acids;aqueous diaminobenzene;high temperature;high pressure