A liquid membrane (pertraction) process of zinc recovery from acidic chloride solutions was studied applying a pertraction in a rotating film contactor (RFC). Tri-n-octylamine (TOA or R3N) dissolved in n-octane was used as a carrier. The influence of the main process parameters, such as disc rotation velocity, hydrochloric acid concentration in the aqueous phases and carrier concentration in the membrane was investigated. Assuming the existence of two thin reaction layers in the feed and stripping solutions, adjacent to both water-oil interfaces, a mathematical model was developed to describe the zinc transport. On the basis of the experimental data obtained under various conditions and the model proposed, it was found that the extraction step is controlled mainly by the mass transfer resistance, whereas the stripping rate of zinc is controlled predominantly by the rate of zinc-carrier complex decomposition in the stripping side reaction layer.