화학공학소재연구정보센터
Biomass & Bioenergy, Vol.23, No.6, 487-493, 2002
Formation of ethanol from carbon monoxide via a new microbial catalyst
A recently discovered clostridial bacteria converts components of synthesis gas (CO, CO2, H-2) into liquid products such as ethanol, butanol and acetic acid. Isolated from an agricultural lagoon, the stability and productivity characteristics of the bacteria were studied in a continuous 4.51 bubble column bioreactor at 37degreesC using artificial blends of CO, CO2, and N-2. Preliminary results on the rates of cell growth, substrate utilization, product formation, and yields of products and cells from CO are discussed. At steady state, apparent yields (mole C in products per mole CO consumed) of ethanol, butanol, and acetic acid were 0.15, 0.075 and 0.025, respectively, and the cell yield was 0.25 g/mol CO. The theoretical yield of ethanol is 0.33 if CO is only utilized for the production of ethanol. The experimental yield of CO2 from CO was approximately 60% compared to the theoretical yield of 67% with ethanol as the sole product. As a comparison with another ethanol-producing bacteria, the results of a similar fermentation study using batch-grown Clostridium ljungdahlii showed yields of 0.062 for ethanol and 0.094 for acetic acid and a cell yield of 1.378 g/mol.