Carboxylate-bridged copper(II)-lanthanicle(III) complexes [{Cu(3)Ln(2)(oda)(6)(H2O)(6)} center dot 12H(2)O](n) (Ln = Dy, Ho, Er, Y; oda = oxydiacetate)

Rizzi AC; Calvo R; Baggio R; Garland MT; Pena O; Perec M

Inorganic Chemistry, Vol.41, No.21, 5609-5614, 2002

Rizzi AC, Calvo R, Baggio R, Garland MT, Pena O, Perec M

The hydrothermal reaction of Ln(2)O(3) (Ln = Dy and Ho), Cu(OAC)(2).2H(2)O, and oxydiacetic acid in the approximate mole ratio of 1:3:8 resulted in the formation of two new members of the isostructural series of polymers formulated as [{Cu(3)Ln(2)(oda)(6)(H2O)(6)}.12H(2)O](n), crystallizing in the hexagonal crystal system, space group P6/mcc (No. 192). Temperature-dependent magnetic susceptibilities and EPR spectra are reported for the heterometallic compounds Cu-Dy 1, Cu-Ho 2, Cu-Er 3, and Cu-Y 4. The results are discussed in terms of the structure of the compounds, the electronic properties of the lanthanide ions, and the exchange interactions between the magnetic ions.