Inorganic Chemistry, Vol.41, No.24, 6178-6180, 2002
Novel luminescent hexanuclear platinum(II) alkynyl complex: Molecular lego from a face-to-face dinuclear platinum(II) building block
A novel luminescent hexanuclear platinum(II) complex, [Pt-2(mu-dppm)(2)(Cequivalent toCC(5)H(4)N)(4){Pt(trpy)}(4)](CF3SO3)(8) (trpy = 2,2':6',2"-terpyridine), was successfully synthesized by using the face-to-face dinuclear platinum(II) ethynylpyridine complex [Pt-2(mu-dppm)(2)(Cequivalent to CC5H4N)(4)] as the building block.