Various water-soluble cationic fluoro copolymers in quaternized form with perfluoroalkyl, amino, and hydroxyl groups were prepared by varying the contents of perfluoroalkyl ethyl acrylate (FA), 2-(dimethylamino) ethyl methacrylate (DAMA), and 2-hydroxyethyl methacrylate (HEMA). The solvent polymerization was carried out in acetone, with the subsequent addition of acetic acid to form a quaternized polymer. Polyurethanes films were prepared by curing aqueous solutions containing water-soluble cationic fluoro copolymers and a blocked isocyanate at 190degreesC. The surface characteristics of the water-soluble cationic fluoro copolymers and the polyurethanes were investigated on the basis of FA and DAMA contents. The contact angles for both water and methylene iodide (MI) on the cationic fluoro copolymer and the polyurethane increase steadily as FA content increases, and decrease gradually with increasing DAMA content. The contact angles on the polyurethane are slightly higher than those on the cationic fluoro copolymer. The cationic fluoro copolymer and the polyurethane with FA content of 40 wt % and DAMA content of <30 wt show extremely low surface free energies of 13-15 dynes/cm.