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Journal of Chemical Thermodynamics, Vol.34, No.10, 1729-1743, 2002
An isoperibol micro-bomb combustion calorimeter for measurement of the enthalpy of combustion. Application to the study of fullerene C-60
A microstatic-bomb combustion calorimeter has been developed from a 1107 Parr semi-micro-bomb. The energy equivalent of this calorimeter is just epsilon(calor) = (687.45 +/- 0.34) J.K-1, which means an uncertainty of 0.05% for the calibration with benzoic acid NIST 39j. This combustion calorimeter has found direct application in the measurement of the enthalpy of combustion of the fullerene C-60, giving Delta(c)U(m)degrees(cr, 298.15 K) = -(25899.1 +/- 14.2) kJ.mol(-1) for this substance.