화학공학소재연구정보센터
Catalysis Today, Vol.77, No.1-2, 51-64, 2002
Steam reforming of hydrocarbon fuels
InnovaTek has developed a proprietary catalyst formulation for the fuel processor that is being developed for use with polymer electrolyte membrane fuel cells. The catalyst has been tested for the steam reforming of various hydrocarbons such as natural gas, iso-octane, retail gasoline, and hexadecane. A 300h continuous test has shown that the catalyst has very stable performance for steam reforming of iso-octane at 800degreesC with a steam/C ratio of 3.6. The same catalyst was also tested for steam reforming hexadecane (a surrogate of diesel) for 73 h as well as natural gas for over 150 h continuously, without deactivation or carbon deposition. Sulfur tolerance of the catalyst was tested using iso-octane containing various concentrations of sulfur. There was no catalyst deactivation after a 220 h continuous test using iso-octane with 100 ppm sulfur. For comparison, a nickel catalyst (12 wt.% Ni/Al2O3) was also tested using different levels of sulfur in iso-octane. The results indicated that the InnovaTek catalyst has a substantially improved sulfur resistance compared to the nickel catalysts currently used for steam reforming. In addition, a variation of the catalyst was also used to reduce CO concentration to < 1% by water gas shift reaction.