This study was focused on the influence of the microstructural properties of a silicon polymer network on its rheological properties. Two commercial silicon oils were mixed in different ratios to form, by hydrosilylation, networks with different crosslink densities. The chemical compositions of the oils were determined by NMR, whereas their molecular weights and viscosities were studied with gel permeation chromatography and viscosimetry, respectively. The different networks were characterized through their crosslink densities. Afterward, the rheological properties were studied. The formulation notably influenced some characteristic values of the rheological behavior: the a-transition temperature and the onset temperature of the caoutchoutic plateau shifted toward higher temperatures as the crosslink density increased, the storage modulus at the onset temperature of the caoutchoutic plateau increased with the crosslink density, and the amplitude of the peak associated with the alpha-transition temperature decreased. These behaviors were explained as follows: as the crosslink density increased, a drastic decrease in the amount of free chains in the network occurred, and both phenomena induced a large decrease in the chain mobility, which might explain the aforementioned behavior.