화학공학소재연구정보센터
Journal of Materials Science, Vol.38, No.4, 633-642, 2003
Correlation of fatigue and creep crack growth in poly(vinyl chloride)
Slow crack growth in PVC pipe was studied in order to develop a methodology for predicting long-term creep fracture from short-term tension-tension fatigue tests. In all cases, the crack propagated continuously through a crack-tip craze. In fatigue, the density of drawn craze fibrils gradually increased with decreased frequency and increased temperature. At the lowest frequency, 0.01 Hz, the fibril density in fatigue approached that in creep. The kinetics of fatigue and creep crack growth followed the conventional Paris law formulations with the same exponent 2.7, da/dt=A(f)DeltaK(I)(2.7), da/dt= BKI2.7, respectively. The effects of frequency, temperature and R-ratio (the ratio of minimum to maximum stress intensity factor in the fatigue loading cycle) on the Paris law prefactors were characterized. Comparison of frequency and R-ratio tests revealed that the fatigue contribution depended on strain rate. Therefore, at each temperature, crack growth rate was modeled as the product of a creep contribution that depended only on the maximum stress intensity factor and a fatigue contribution that depended on strain rate: (da/dt) = BKI,max2.7 (1 + C(epsilon) over dot), where B is the prefactor in the Paris law for creep and C is a coefficient defining the strain rate sensitivity. A linear correlation allowed extrapolation of the creep prefactor (B) from fatigue data. The extrapolated values were systematically higher than the values measured directly from creep and only converged at T-g. The difference was attributed to damage of the craze fibrils during crack closure upon unloading in the fatigue cycle. (C) 2003 Kluwer Academic Publishers.