화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of the Korean Industrial and Engineering Chemistry, Vol.14, No.1, 1-15, February, 2003
Export Citation
이산화탄소 수소화 반응을 위한 촉매의 연구개발 현황
Research and Development of Catalysts for Carbon Dioxide Hydrogenation
전종기, 박영권1, 임선기2, †
  • 동양대학교 시스템화학생명공학과, 경북 750-711
  • 1서울시립대학교 환경공학부, 서울 130-743
  • 2한국과학기술원 생명화학공학과, 대전 305-701
Jong-ki Jeon, Young-Kwon Park1, and Son-Ki Ihm2, †
  • Department of Chemical Engineering, DongYang University, YoungJou, Kyungbook 750-711, Korea
  • 1Faculty of Environmental Engineering, University of Seoul, Dongdaemun-Gu, Seoul 130-743, Korea
  • 2Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, Yusong-Gu, Daejeon 305-701, Korea
E-mail:
초록
온실효과를 유발하는 이산화탄소는 매우 풍부한 탄소원이며 대기 중의 농도가 꾸준하게 증가하고 있다. 대기 중의 이산화탄소의 농도를 제어하기 위해서 이산화탄소를 화학반응을 통하여 유용한 화합물로 전환하는 기술이 집중적으로 연구되고 있다. 짧은 시간 내에 많은 양의 이산화탄소를 처리할 수 있다는 이점 때문에 이산화탄소의 수소화 반응이 가장 효과적인 공정으로 제안되고 있다. 금속/금속산화물 촉매 또는 금속/금속산화물과 제올라이트가 조합된 혼성촉매를 사용하여 이산화탄소와 수소로부터 함산소 화합물이나 탄화수소를 선택적으로 합성할 수 있다. 본 고에서는 메탄올, 파라핀, 올레핀, 디메틸에테르, 에탄올 등의 효율적인 합성을 위한 촉매의 최근 연구 및 개발 현황을 집중적으로 다루었다.
Carbon dioxide, which causes greenhouse effect, is one of the most abundant carbon resources avaiable, and its concentration in the atmosphere has steadily increased. In order to control the concentration of carbon dioxide in the air, various kinds of technologies that transform carbon dioxide into useful products via chemical reactions have been studied intensively. Recently the catalytic hydrogenation of carbon dioxide has been proposed as one of the most effective processes because it can treat a large amount of carbon dioxide in a relatively short period of time. By using metal/metal oxide catalysts or hybrid catalysts composed of metal/metal oxide and zeolite, the selective synthesis of oxygenates or hydrocarbons from carbon dioxide and hydrogen was realized. In this review, recent researches and developments of catalysts for the effective synthesis of methanol, paraffin, olefin, dimethylether, ethanol and others are introduced.
Keywords:carbon dioxide hydrogenation;methanol;hydrocarbon;hybrid catalyst
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