All-solid-state lithium secondary battery with ceramic/polymer composite electrolyte

Kobayashi Y; Miyashiro H; Takeuchi T; Shigemura H; Balakrishnan N; Tabuchi M; Kageyama H; Iwahori T

Solid State Ionics, Vol.152, 137-142, 2002

DOI10.1016/S0167-2738(02)00366-1 Export Citation

All-solid-state lithium secondary battery with ceramic/polymer composite electrolyte

Kobayashi Y, Miyashiro H, Takeuchi T, Shigemura H, Balakrishnan N, Tabuchi M, Kageyama H, Iwahori T

Dense lithium lanthanum titanate, (Li,La)TiO3, Pellets were prepared using a spark-plasma sintering (SPS) method. The obtained (Li,La)TiO3 pellets showed relatively high lithium ion conductivity, typically 10(-3) S cm(-1) at 22 degreesC, with an activation energy of 30.1 kJ mol(-1). Lithium manganese oxide, LiMn2O4, was deposited on (Li,La)TiO3 pellets by an electrostatic spray deposition (ESD) method at 400 degreesC without significant formation of by-products at the interface (Li,La)TiO3/ LiMn2O4. An all-solid-state battery system, LiMn2O4/(Li,La)TiO3/SPE/Li, where a solid polymer electrolyte (SPE) was sandwiched between (Li,La)TiO3 and Li, showed good charge/discharge characteristics over 100 cycles at 60 degreesC.

Keywords:all-solid-state lithium batteries;lithium lanthanum titanate;lithium manganese oxide;spark-plasma sintering;electrostatic spray deposition