화학공학소재연구정보센터
Thin Solid Films, Vol.422, No.1-2, 150-154, 2002
Improved interface properties of yttrium oxide buffer layer on silicon substrate for ferroelectric random access memory applications
In this paper, we report upon an investigation into the feasibility of Y2O3 films as buffer layers for metal ferroelectric insulator semiconductor type capacitors. Buffer layers were prepared by a two-step process of low temperature film growth using the RF reactive magnetron sputtering method and subsequent rapid thermal annealing. By applying an yttrium metal seed layer of 4 nm, unwanted SiO2 layer generation was successfully suppressed at the interface between the buffer layer and the Si substrate. Increasing the post-annealing temperature above 700 degreesC reduced the surface roughness of the Y2O3 films, and increasing the 02 partial pressure from 10 to 20% increased the surface roughness from 4.0 to 15.1 nm. The Y2O3 films, prepared using an 02 partial pressure of 20% and annealed at 900 degreesC, exhibited the best surface roughness characteristics of the samples studied. For a substrate temperature above 400 degreesC and an 02 partial pressure of 20%, we observed that a cubic Y2O3 phase dominated the Xray diffraction spectra. The lowest lattice mismatch achieved between the Y2O3 film and the Si substrate was 1.75%. By using a two-step process, we reduced the leakage current density of Y2O3 films by two orders of magnitude and the D,, to as low as 8.72 X 10(10) cm(-2) eV(-1). A Y2O3 buffer layer grown at 400 degreesC in a 20% O-2 partial pressure and rapidly annealed at 900 degreesC in an oxygen enviroment exhibited the best overall properties for a single transistor ferroelectric random access memory.