Effect of mass transfer on the transient free convection flow of a dissipative fluid along a semi-infinite vertical plate in presence of constant heat flux, is studied by solving coupled non-linear system of partial differential equations, using Crank-Nicolson technique which is stable and convergent. Transient temperature, concentration and velocity profiles, local and average skin-friction, Nusselt number and Sherwood number are shown graphically for air. The effects of epsilon, viscous dissipative parameter, Schmidt number, buoyancy ratio parameter on the transient state are discussed.