화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.11, No.3, 157-162, June, 2003
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Gas Separation Properties of 6FDA-Based Polyimide Membranes with a Polar Group
Sang-Hee Park, Kwang-Je Kim†, Won-Wook So, Sang-Jin Moon, and Soo-Bok Lee
  • Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology, P.O. Box 107 Yousong, Daejeon 305-600, Korea
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6FDA-based polyimides were prepared from the thermal imidization reaction of 6FDA with diamines of BAPAF, DAP, and DABA having a polar group of hydroxyl or carboxyl. Properties of the dense polyimide membranes were characterized and their gas permeation properties for H2, CO2, O2, N2, and CH4 were investigated. Permeabilities, diffusion coefficients and diffusivity selectivities of polar group-containing polyimide membranes including 6FDA-BAPAF, 6FDA-DAP, and 6FDA-DABA polymer for the gases did not change largely. The separation properties of 6FDA-TrMPD polyimide membrane used as a reference polymer were compared with those of the polyimide membranes mentioned above. It was found that the polyimides of 6FDA-BAPAF, 6FDA-DAP, and 6FDA-DABA, which were soluble in alcohol or/and 2-methoxyethanol, could be applicable to the preparation of a dense composite membrane by dip-coating method.
Keywords:6FDA;polyimide membrane;gas separation;polar group;separation properties
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